Space Charge Layer Effect in Solid State Ion Conductors and Lithium Batteries: Principle and Perspective | |
Chen, Cheng; Guo, Xiangxin | |
刊名 | ACTA CHIMICA SLOVENICA
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2016 | |
卷号 | 63期号:3页码:489-495 |
关键词 | Space charge layer Defect chemistry Interfacial resistance All solid state lithium battery |
英文摘要 | The space charge layer (SCL) effects were initially developed to explain the anomalous conductivity enhancement in composite ionic conductors. They were further extended to qualitatively as well as quantitatively understand the interfacial phenomena in many other ionic-conducting systems. Especially in nanometre-scale systems, the SCL effects could be used to manipulate the conductivity and construct artificial conductors. Recently, existence of such effects either at the electrolyte/cathode interface or at the interfaces inside the composite electrode in all solid state lithium batteries (ASSLB) has attracted attention. Therefore, in this article, the principle of SCL on basis of defect chemistry is first presented. The SCL effects on the carrier transport and storage in typical conducting systems are reviewed. For ASSLB, the relevant effects reported so far are also reviewed. Finally, the perspective of interface engineer related to SCL in ASSLB is addressed. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | SOGGY-SAND ELECTROLYTES ; ELECTRICAL-CONDUCTIVITY ; INTERFACIAL MODIFICATION ; SECONDARY BATTERIES ; HETEROSTRUCTURES ; REGIONS ; CATHODE ; STORAGE ; PHASE ; EQUILIBRIUM |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000388256900008 |
内容类型 | 期刊论文 |
源URL | [http://ir.sic.ac.cn/handle/331005/21971] ![]() |
专题 | 上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文 |
作者单位 | Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Ding Xi Rd, Shanghai 200050, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Cheng,Guo, Xiangxin. Space Charge Layer Effect in Solid State Ion Conductors and Lithium Batteries: Principle and Perspective[J]. ACTA CHIMICA SLOVENICA,2016,63(3):489-495. |
APA | Chen, Cheng,&Guo, Xiangxin.(2016).Space Charge Layer Effect in Solid State Ion Conductors and Lithium Batteries: Principle and Perspective.ACTA CHIMICA SLOVENICA,63(3),489-495. |
MLA | Chen, Cheng,et al."Space Charge Layer Effect in Solid State Ion Conductors and Lithium Batteries: Principle and Perspective".ACTA CHIMICA SLOVENICA 63.3(2016):489-495. |
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