Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin

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	Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin
	Guo WH(郭文豪); Min QQ(闵巧桥); Gu JW(顾继伟); Zhang XG(张新刚)
刊名	Angew. Chem.-Int. Edit.
	2015
卷号	54 期号:31 页码:9075-9078
其他题名	铑催化下多氟芳烃邻位选择性C-F键硼化
通讯作者	张新刚
英文摘要	An ortho-selective CF bond borylation between N-heterocycle-substituted polyfluoroarenes and Bpin-Bpin with simple and commercially available [Rh(cod)(2)]BF4 as a catalyst is now reported. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, even toward monofluoroarene, thus providing a facile access to a wide range of borylated fluoroarenes that are useful for photoelectronic materials. Preliminary mechanistic studies reveal that a Rh-III/V catalytic cycle via a key intermediate rhodium(III) hydride complex [(H)(RhLn)-L-III(Bpin)] may be involved in the reaction.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/anie.201500124
语种	英语
WOS记录号	WOS:000358501500037
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39733]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	中科院上海有机化学研究所, 有机氟化学重点实验室
推荐引用方式 GB/T 7714	Guo WH,Min QQ,Gu JW,et al. Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin[J]. Angew. Chem.-Int. Edit.,2015,54(31):9075-9078.
APA	郭文豪,闵巧桥,顾继伟,&张新刚.(2015).Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin.Angew. Chem.-Int. Edit.,54(31),9075-9078.
MLA	郭文豪,et al."Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin".Angew. Chem.-Int. Edit. 54.31(2015):9075-9078.