Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes | |
Yu W(余伟)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1 | |
刊名 | Adv. Synth. Catal. |
2015 | |
卷号 | 357期号:9页码:2039-2044 |
其他题名 | 银参与未活化烯烃的氧化三氟甲基化反应 |
通讯作者 | 卿凤翎 |
英文摘要 | An efficient regioselective fluorotrifluoro-methylation of unactivated alkenes has been developed. The reaction of alkenes with (trifluoromethyl) trimethylsilane (TMSCF3) and Selectfluor in the presence of silver trifluoromethanesulfonate (AgOTf), cesium fluoride (CsF), and iodobenzene diacetate [PhI(OAc)(2)] in N,N-dimethylformamide (DMF) at -20 degrees C gave the corresponding fluorotrifluoromethylated products in moderate to good yields. The silver salt turns out to be crucial for this transformation. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/adsc.201500027 |
语种 | 英语 |
WOS记录号 | WOS:000356373200008 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39728] |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 有机氟化学重点实验室 2.东华大学 |
推荐引用方式 GB/T 7714 | Yu W,Xu XH,Qing FL. Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes[J]. Adv. Synth. Catal.,2015,357(9):2039-2044. |
APA | 余伟,徐修华,&卿凤翎.(2015).Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes.Adv. Synth. Catal.,357(9),2039-2044. |
MLA | 余伟,et al."Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes".Adv. Synth. Catal. 357.9(2015):2039-2044. |
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