Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex

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	Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex
	Chen YJ(陈亚静); Cui Z(崔哲); Feng CG(冯陈国); Lin GQ(林国强)
刊名	Adv. Synth. Catal.
	2015
卷号	357 期号:13 页码:2815-2820
其他题名	銠-双烯配体催化的杂环芳基硼酸对芳基亚胺的不对称加成
通讯作者	冯陈国
英文摘要	An enantioselective rhodium-catalyzed 1,2-addition of heteroarylboronates to aryl N-tosylimines and N-nosylimines has been developed. Our chiral rhodium-diene catalyst showed high efficiency in the stereochemical control of this reaction. Under the optimal reaction conditions, a variety of boronates bearing pyridinyl, furyl or thienyl groups were successfully reacted with aryl imines. The boronate type, with balance of the stability and reactivity, is critical for achieving high reaction yields in this reaction.
学科主题	天然产物有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/adsc.201500147
语种	英语
WOS记录号	WOS:000362527100007
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39806]
专题	上海有机化学研究所_中科院天然产物有机化学重点实验室
作者单位	中科院上海有机化学研究所, 天然产物有机合成化学重点实验室
推荐引用方式 GB/T 7714	Chen YJ,Cui Z,Feng CG,et al. Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex[J]. Adv. Synth. Catal.,2015,357(13):2815-2820.
APA	陈亚静,崔哲,冯陈国,&林国强.(2015).Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex.Adv. Synth. Catal.,357(13),2815-2820.
MLA	陈亚静,et al."Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex".Adv. Synth. Catal. 357.13(2015):2815-2820.