[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones | |
Han L(韩磊)1; Lei Y(雷洋)1; Xing P(邢萍)1; Zhao XL(赵小龙)1; Jiang B(姜标)1 | |
刊名 | J. Org. Chem.
![]() |
2015 | |
卷号 | 80期号:8页码:3752-3757 |
其他题名 | [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones |
通讯作者 | 姜标 |
英文摘要 | Copper-catalyzed asymmetric conjugate addition of diethylzinc to chalcones could be realized by using [2.2]paracyclophane-derived monodentate phosphoramidite ligands. The excellent yield and enantioselectivity (up to 98% yield and 95% enantiomeric excess) could be realized with low catalyst loading of 1.0 mol % and low ligand loading of 1.2%. |
学科主题 | 天然产物有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jo502715f |
语种 | 英语 |
WOS记录号 | WOS:000353315000003 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39783] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
作者单位 | 1.中科院上海有机化学研究所, 天然产物有机合成化学重点实验室 2.中科院上海高等研究院 |
推荐引用方式 GB/T 7714 | Han L,Lei Y,Xing P,et al. [2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones[J]. J. Org. Chem.,2015,80(8):3752-3757. |
APA | 韩磊,雷洋,邢萍,赵小龙,&姜标.(2015).[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones.J. Org. Chem.,80(8),3752-3757. |
MLA | 韩磊,et al."[2.2]Paracyclophane-Derived Monodentate Phosphoramidite Ligands for Copper-Catalyzed Asymmetric Conjugate Addition of Diethylzinc to Substituted Chalcones".J. Org. Chem. 80.8(2015):3752-3757. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论