A Novel Allyl Transfer Coupled with a Grob Fragmentation

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	A Novel Allyl Transfer Coupled with a Grob Fragmentation
	Li SG(李绍刚); Chen HJ(陈慧君); Yang YY(杨洋洋); Wu WJ(武文菊); Wu YK(伍贻康)
刊名	Chem.-Asian J.
	2015
卷号	10 期号:11 页码:2333-2336
其他题名	一个与Grob碎裂相偶联的新颖烯丙基重排反应
通讯作者	伍贻康
英文摘要	A novel acid-promoted rearrangement is disclosed. In the previously unknown transformation, an allyl group migrated to an in situ formed carbocation stabilized by an electron-rich aryl or heteroaryl group, resulting in a stereoselective intramolecular Grob fragmentation. The outcome of the rearrangement observed with an array of substrates can be satisfactorily rationalized using a working hypothesis with the aid of a six-membered transition state similar to those proposed for the anionic oxy-Cope or oxonia-Cope rearrangements, but involving only one instead of two double bonds.
学科主题	生命有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1002/asia.201500728
语种	英语
WOS记录号	WOS:000363472800003
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39530]
专题	上海有机化学研究所_生命有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 生命有机化学国家重点实验室
推荐引用方式 GB/T 7714	Li SG,Chen HJ,Yang YY,et al. A Novel Allyl Transfer Coupled with a Grob Fragmentation[J]. Chem.-Asian J.,2015,10(11):2333-2336.
APA	李绍刚,陈慧君,杨洋洋,武文菊,&伍贻康.(2015).A Novel Allyl Transfer Coupled with a Grob Fragmentation.Chem.-Asian J.,10(11),2333-2336.
MLA	李绍刚,et al."A Novel Allyl Transfer Coupled with a Grob Fragmentation".Chem.-Asian J. 10.11(2015):2333-2336.