CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes

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	CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes
	Tang XJ(汤鑫军)1; Huang X(黄鑫)1; Cao T(曹陶)1; Han YL(韩玉林)1; Jiang XG(姜兴国)1; Lin WL(林渭龙)1; Tang Y(唐阳)1; Zhang JS(张加生)1; Yu Q(俞琼)1; Fu CL(傅春玲)1
刊名	Org. Chem. Front.
	2015
卷号	2 期号:6 页码:688-691
其他题名	CuBr2催化的对映选择性合成高官能团化的天然产物联烯的方法
通讯作者	麻生明
英文摘要	Here we show the CuBr2-catalyzed approach for highly enantioselective synthesis (90-98% ee) of allenes bearing a very broad array of unmasked synthetically attractive functionalities from aldehydes and terminal alkynyl bearing reactive functionalities with the absolute configuration controlled by applying readily available (R)- or ( S)-alpha,alpha-diphenylprolinol. Following this protocol, the highly enantioselective synthesis of some naturally occurring allenes loaded with reactive functionalities becomes simple: a terminal alkyne plus an aldehyde. In comparison, they were reported to be synthesized either from similar level generic chemicals with much more steps or in lower ees.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5qo00084j
语种	英语
WOS记录号	WOS:000364445900012
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39661]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所, 金属有机化学国家重点实验室 2.浙江大学 3.华东师范大学
推荐引用方式 GB/T 7714	Tang XJ,Huang X,Cao T,et al. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes[J]. Org. Chem. Front.,2015,2(6):688-691.
APA	汤鑫军.,黄鑫.,曹陶.,韩玉林.,姜兴国.,...&麻生明.(2015).CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes.Org. Chem. Front.,2(6),688-691.
MLA	汤鑫军,et al."CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes".Org. Chem. Front. 2.6(2015):688-691.