Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis

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	Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis
	Chen WQ(陈伟强); Yang Q(杨琴); Zhou T(周添); Tian QS(田青杉); Zhang GZ(张国柱)
刊名	Org. Lett.
	2015
卷号	17 期号:21 页码:5236-5239
其他题名	铬催化的不对称合成α亚甲基γ丁内酯
通讯作者	张国柱
英文摘要	Enantioenriched alpha-exo-methylene gamma-butyrolactones have been obtained via a two-step sequence consisting of a highly enantioselective chromium-catalyzed carbonyl 2-(alkoxycarbonyl)allylation and lactonization. A variety of functional groups are compatible under the mild reaction conditions. The synthetic utility of this methodology was demonstrated by two short derivatization transformations and the enantioselective synthesis of (+)-methylenolactocin.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/acs.orglett.5b02597
语种	英语
WOS记录号	WOS:000364434900023
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39653]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Chen WQ,Yang Q,Zhou T,et al. Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis[J]. Org. Lett.,2015,17(21):5236-5239.
APA	陈伟强,杨琴,周添,田青杉,&张国柱.(2015).Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis.Org. Lett.,17(21),5236-5239.
MLA	陈伟强,et al."Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis".Org. Lett. 17.21(2015):5236-5239.