Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction | |
Zheng J(郑军); Wang SB(王少博); Zheng C(郑超); You SL(游书力) | |
刊名 | J. Am. Chem. Soc.
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2015 | |
卷号 | 137期号:15页码:4880-4883 |
其他题名 | 铑催化C(sp2)-H官能化/环化反应实现萘酚的不对称去芳构化 |
通讯作者 | 游书力 |
英文摘要 | A Rh-catalyzed enantioselective dearomatization of 1-aryl-2-naphthols with internal alkynes via C-H functionalization reaction was achieved. In the presence of a chiral Cp/Rh catalyst and combined oxidants of Cu(OAc)(2) and air (oxygen), various highly enantioenriched spirocyclic enones bearing an all-carbon quaternary stereogenic center could be synthesized in 33-98% yields with up to 97:3 er. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jacs.5b01707 |
语种 | 英语 |
WOS记录号 | WOS:000353606700002 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39599] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所, 金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Zheng J,Wang SB,Zheng C,et al. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction[J]. J. Am. Chem. Soc.,2015,137(15):4880-4883. |
APA | 郑军,王少博,郑超,&游书力.(2015).Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction.J. Am. Chem. Soc.,137(15),4880-4883. |
MLA | 郑军,et al."Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction".J. Am. Chem. Soc. 137.15(2015):4880-4883. |
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