Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction
	Zheng J(郑军); Wang SB(王少博); Zheng C(郑超); You SL(游书力)
刊名	J. Am. Chem. Soc.
	2015
卷号	137 期号:15 页码:4880-4883
其他题名	铑催化C(sp2)-H官能化/环化反应实现萘酚的不对称去芳构化
通讯作者	游书力
英文摘要	A Rh-catalyzed enantioselective dearomatization of 1-aryl-2-naphthols with internal alkynes via C-H functionalization reaction was achieved. In the presence of a chiral Cp/Rh catalyst and combined oxidants of Cu(OAc)(2) and air (oxygen), various highly enantioenriched spirocyclic enones bearing an all-carbon quaternary stereogenic center could be synthesized in 33-98% yields with up to 97:3 er.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jacs.5b01707
语种	英语
WOS记录号	WOS:000353606700002
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39599]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所, 金属有机化学国家重点实验室
推荐引用方式 GB/T 7714	Zheng J,Wang SB,Zheng C,et al. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction[J]. J. Am. Chem. Soc.,2015,137(15):4880-4883.
APA	郑军,王少博,郑超,&游书力.(2015).Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction.J. Am. Chem. Soc.,137(15),4880-4883.
MLA	郑军,et al."Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp(2))-H Functionalization/Annulation Reaction".J. Am. Chem. Soc. 137.15(2015):4880-4883.