Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer

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	Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
	Lu GL(陆国林)1; Jiang XJ(蒋晓军)1; Li YJ(李永军)1; Lv XL(吕绪良)1; Huang XY(黄晓宇)1
刊名	RSC Adv.
	2015
卷号	5 期号:91 页码:74947-74952
其他题名	Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer
通讯作者	吕绪良 ; 黄晓宇
英文摘要	Two well-defined perfluorocyclobutyl aryl ether-based amphiphilic graft copolymers containing a hydrophobic poly(2-methyl-1,4-bistrifluorovinyloxybenzene) (PMBTFVB) backbone and hydrophilic poly(N-isopropylacrylamide) (PNIPAM) side chains were synthesized via sequential thermal step-growth [2 pi + 2 pi] cycloaddition polymerization of 2-methyl-1,4-bistrifluorovinyloxybenzene and atom transfer radical polymerization (ATRP) of N-isopropylacrylamide (NIPAM). PMBTFVB homopolymer was converted to PMBTFVB-Cl macroinitiator by monochlorination of the pendant methyls with N-chlorosuccinimide and benzoyl peroxide. A grafting-from strategy was then adopted for preparing well-defined PMBTFVB-g-PNIPAM graft copolymers with narrow molecular weight distributions (M-w/M-n < 1.30) via ATRP of NIPAM, which was initiated by the Cl-containing macroinitiator. The critical micelle concentration (cmc) was determined by a fluorescence probe technique and the effects of salinity on the cmc of PMBTFVB-g-PNIPAM graft copolymer were also investigated.
学科主题	高分子化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5ra14302k
语种	英语
WOS记录号	WOS:000361116500096
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39857]
专题	上海有机化学研究所_高分子材料研究室
作者单位	1.中科院上海有机化学研究所, 有机功能分子合成与组装化学重点实验室 2.解放军理工大学
推荐引用方式 GB/T 7714	Lu GL,Jiang XJ,Li YJ,et al. Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer[J]. RSC Adv.,2015,5(91):74947-74952.
APA	陆国林,蒋晓军,李永军,吕绪良,&黄晓宇.(2015).Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer.RSC Adv.,5(91),74947-74952.
MLA	陆国林,et al."Synthesis and self-assembly of PMBTFVB-g-PNIPAM fluorine-containing amphiphilic graft copolymer".RSC Adv. 5.91(2015):74947-74952.