Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent

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	Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent
	Wang ZS(王长胜)1; Wang HY(王昊阳)1; Yao C(姚成)1
刊名	RSC Adv.
	2015
卷号	5 期号:31 页码:24783-24787
其他题名	铜催化的亲电三氟甲基化试剂与有机锌试剂的三氟甲基化反应
通讯作者	姚成
英文摘要	A copper-catalyzed trifluoromethylation of aryl, vinyl and alkyl zinc reagents with Togni's reagent was described. Mechanistic studies indicated that the aryl group is initially transferred from the zinc reagent to hypervalent iodine to form a tri-substituted hypervalent iodine intermediate. Consequent reductive-elimination via a concerted bond-forming step and/or radical pathway from this intermediate generates the trifluoromethylated arenes.
学科主题	有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1039/c5ra02279g
语种	英语
WOS记录号	WOS:000351236300097
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39687]
专题	上海有机化学研究所_分析化学研究室
作者单位	1.南京工业大学 2.中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Wang ZS,Wang HY,Yao C. Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent[J]. RSC Adv.,2015,5(31):24783-24787.
APA	王长胜,王昊阳,&姚成.(2015).Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent.RSC Adv.,5(31),24783-24787.
MLA	王长胜,et al."Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent".RSC Adv. 5.31(2015):24783-24787.