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	Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid
	Xia, Yun-Tao1,2; Sun, Xiao-Tao1,2; Zhang, Ling1,2; Luo, Kai1,2; Wu, Lei1,2,3,4
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2016-11-21
卷号	22期号:48页码:17151-17155
关键词	diboronic acid hydrogen atom transfer metal-free nitrogen heterocycles water
英文摘要	A hydrogenation of N-heterocycles mediated by diboronic acid with water as the hydrogen atom source is reported. A variety of N-heterocycles can be hydrogenated with medium to excellent yields within 10min. Complete deuterium incorporation from stoichiometric D2O onto substrates further exemplifies the H/D atom sources. Mechanism studies reveal that the reduction proceeds with initial 1,2-addition, in which diboronic acid synergistically activates substrates and water via a six-membered ring transition state.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/35697]
专题	化学研究所_其它
作者单位	1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China 2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Xia, Yun-Tao,Sun, Xiao-Tao,Zhang, Ling,et al. Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(48):17151-17155.
APA	Xia, Yun-Tao,Sun, Xiao-Tao,Zhang, Ling,Luo, Kai,&Wu, Lei.(2016).Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid.CHEMISTRY-A EUROPEAN JOURNAL,22(48),17151-17155.
MLA	Xia, Yun-Tao,et al."Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid".CHEMISTRY-A EUROPEAN JOURNAL 22.48(2016):17151-17155.

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