Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group

	Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group
	Zhang, Geng-Wu 1,2; Li, Peng-Fei 1; Meng, Zheng 1,2; Wang, Han-Xiao 1,2; Han, Ying 1; Chen, Chuan-Feng 1
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016-04-18
卷号	55 期号:17 页码:5304-5308
关键词	chiral resolution enantioselective recognition host-guest chemistry macrocycles triptycenes
英文摘要	A new class of chiral macrocyclic arene composed of three chiral 2,6-dihydroxyltriptycene subunits bridged by methylene groups was designed and synthesized. Structural studies showed that the macrocyclic molecule adopts a hex-nut-like structure with a helical chiral cavity and highly fixed conformation. Efficient resolution was achieved through the introduction of chiral auxiliaries to give a couple of enantiopure macrocycles, which exhibited high enantioselectivity towards three pairs of chiral compounds containing a trimethylamino group.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/36011]
专题	化学研究所_分子识别与功能实验室
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Geng-Wu,Li, Peng-Fei,Meng, Zheng,et al. Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(17):5304-5308.
APA	Zhang, Geng-Wu,Li, Peng-Fei,Meng, Zheng,Wang, Han-Xiao,Han, Ying,&Chen, Chuan-Feng.(2016).Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(17),5304-5308.
MLA	Zhang, Geng-Wu,et al."Triptycene-Based Chiral Macrocyclic Hosts for Highly Enantioselective Recognition of Chiral Guests Containing a Trimethylamino Group".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.17(2016):5304-5308.