Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O | |
Liu, YQ (Liu, Yaqin); Chen, ZH (Chen, Zhaohui); Zhang, ZZ (Zhang, Zhizhong); Wang, Y (Wang, Ying); Dong, XY (Dong, Xiaoyu); Yang, ZH (Yang, Zhihua)![]() | |
刊名 | MATERIALS RESEARCH BULLETIN
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2016 | |
卷号 | 83期号:11页码:423-427 |
关键词 | Optical materials Crystal growth Optical properties X-ray diffraction Crystal structure |
英文摘要 | Single crystal of Li(H2O)(4)B(OH)(4)center dot 2H(2)O has been synthesized via hydrothermal method and its structure was determined by single crystal X-ray diffraction. The space group of Li(H2O)(4)B(OH)(4)center dot 2H(2)O is P3 with cell parameters a = b = 6.5601(4)angstrom, c= 6.1748(3)angstrom, and Z=1. The crystal lattice structure is composed of four B(OH)(4) tetrahedra, one Li(H2O)(4) tetrahedron and two isolated water molecules. Powder X-ray diffraction (XRD), infrared (IR) spectroscopy, UV-vis-IR diffuse reflectance spectroscopy, powder second harmonic generation (SHG) measurements and TG/DSC analysis were performed for the title compound. It reveals that the SHG efficiencies of Li(H2O)(4)B(OH)(4)center dot 2H(2)O is about 0.8 times that of KH2PO4 (KDP). The direction and magnitude of the dipole moments in BO4 and LiO4 units of Li(H2O)(4)B(OH)(4)center dot 2H(2)O have been quantified using the bond-valence approach, which shows that the SHG response originates from the cooperation of BO4 and LiO4 units along c axis. |
收录类别 | SCI |
WOS记录号 | WOS:000382793400057 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/4630] ![]() |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
作者单位 | 1.Xinjiang Univ, Phys & Chem Detecting Ctr, 666 Shengli Rd, Urumqi 830046, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Xinjiang Inst Engn, Engn Dept Chem & Environm, 236 Nanchang Rd, Urumqi 830091, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, YQ ,Chen, ZH ,Zhang, ZZ ,et al. Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O[J]. MATERIALS RESEARCH BULLETIN,2016,83(11):423-427. |
APA | Liu, YQ ,Chen, ZH ,Zhang, ZZ ,Wang, Y ,Dong, XY ,&Yang, ZH .(2016).Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O.MATERIALS RESEARCH BULLETIN,83(11),423-427. |
MLA | Liu, YQ ,et al."Synthesis, structure and properties of nonlinear optical crystal Li (H2O)(4)B(OH)(4)center dot 2H(2)O".MATERIALS RESEARCH BULLETIN 83.11(2016):423-427. |
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