Spectroscopic, and thermal studies of some new binuclear transition metal(II) complexes with hydrazone ligands containing acetoacetanilide and isoxazole

CORC > 上海光学精密机械研究所 > 中国科学院上海光学精密机械研究所 > 高密度光存储技术实验室

	Spectroscopic, and thermal studies of some new binuclear transition metal(II) complexes with hydrazone ligands containing acetoacetanilide and isoxazole
	Chen ZM(陈志敏) ; Wu YQ(吴谊群) ; Gu DH(顾冬红) ; Gan FX(干福熹)
刊名	spectroc. acta pt. a
	2007
卷号	68 期号:3 页码:918
关键词	hydrazone Metal(II) complexes spin-coating film absorption spectra thermal property
ISSN号	1386-1425
中文摘要	a new chelating ligand, 2-(2-(5-tert-butylisoxazol-3-yl)hydrazono)-n-(2,4-dimethylphenyl)-3-oxobutanamide (hl), and its four binuclear transition metal complexes, m-2(l)(2) (mu-och3)(2) [m = ni(ii), co(ii), cu(ii), zn(ii)], were synthesized using the procedure of diazotization, coupling and metallization. their structures were postulated based on elemental analysis, h-1 nmr, maldi-ms, ft-ir spectra and uv-vis electronic absorption spectra. smooth films of these complexes on k9 glass substrates were prepared using the spin-coating method and their absorption properties were evaluated. the thermal properties of the metal(ii) complexes were investigated by thermogravimetry (tg) and differential scanning calorimetry (dsc. different thermodynamic and kinetic parameters namely activation energy (e
学科主题	光存储
收录类别	EI
语种	英语
WOS记录号	WOS:000250607900079
公开日期	2009-09-22
内容类型	期刊论文
源URL	[http://ir.siom.ac.cn/handle/181231/3989]
专题	上海光学精密机械研究所_高密度光存储技术实验室
推荐引用方式 GB/T 7714	Chen ZM,Wu YQ,Gu DH,et al. Spectroscopic, and thermal studies of some new binuclear transition metal(II) complexes with hydrazone ligands containing acetoacetanilide and isoxazole[J]. spectroc. acta pt. a,2007,68(3):918, 926.
APA	陈志敏,吴谊群,顾冬红,&干福熹.(2007).Spectroscopic, and thermal studies of some new binuclear transition metal(II) complexes with hydrazone ligands containing acetoacetanilide and isoxazole.spectroc. acta pt. a,68(3),918.
MLA	陈志敏,et al."Spectroscopic, and thermal studies of some new binuclear transition metal(II) complexes with hydrazone ligands containing acetoacetanilide and isoxazole".spectroc. acta pt. a 68.3(2007):918.