Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells

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	Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells
	Shi Ji-Fu 1; Huang Qi-Zhang 1,2; Wan Qing-Cui 1; Xu Xue-Qing1 ; Li Chun-Sheng 3; Xu Gang1
刊名	acta physico-chimica sinica
	2016-04-15
卷号	32 期号:4 页码:822-827
关键词	Quantum-dot-sensitized solar cell Ionic liquid electrolyte 1-Methyl-3-propylimidazolium sulfide Application temperature Efficiency
英文摘要	we report the preparation and application of a 1-methyl-3-propylimidazolium sulfide-based ionic liquid electrolyte for quantum-dot-sensitized solar cells. by optimizing the concentrations of s and na2s, a considerable conductivity of 12.96 ms.cm(-1) is achieved at 25 degrees c. differential scanning calorimetry indicates that the glass transition temperature of the electrolyte is -85 degrees c. the quantum-dot-sensitized solar cell assembled with this ionic liquid electrolyte displays a high energy conversion efficiency (eta) of 3.03% at 25 c, which is comparable to the efficiency of quantum-dot-sensitized solar cells using a water-based polysulfide electrolyte (q = 3.34%). due to the favorable thermal properties of this ionic liquid electrolyte (lower glass transition temperature and nonvolatility at higher temperatures), the quantum-dot-sensitized solar cell maintains satisfactory eta even at -20 degrees c (eta = 2.32%) and 80 degrees c (eta = 1.90%), which is superior to the cell using the water based polysulfide electrolyte.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	highly efficient ; polysulfide electrolyte
收录类别	SCI
语种	英语
WOS记录号	WOS:000374712500001
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/11387]
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangdong Key Lab New & Renewable Energy Res & De, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.North China Univ Sci & Technol, Coll Chem Engn, Tangshan 063009, Hebei Province, Peoples R China
推荐引用方式 GB/T 7714	Shi Ji-Fu,Huang Qi-Zhang,Wan Qing-Cui,et al. Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells[J]. acta physico-chimica sinica,2016,32(4):822-827.
APA	Shi Ji-Fu,Huang Qi-Zhang,Wan Qing-Cui,Xu Xue-Qing,Li Chun-Sheng,&Xu Gang.(2016).Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells.acta physico-chimica sinica,32(4),822-827.
MLA	Shi Ji-Fu,et al."Sulfide-Based Ionic Liquid Electrolyte Widening the Application Temperature Range of Quantum-Dot-Sensitized Solar Cells".acta physico-chimica sinica 32.4(2016):822-827.