激光剥蚀-电感耦合等离子体-原子发射光谱/质谱法分析中国古代钾玻璃组分

CORC > 上海光学精密机械研究所 > 中国科学院上海光学精密机械研究所 > 高密度光存储技术实验室

	激光剥蚀-电感耦合等离子体-原子发射光谱/质谱法分析中国古代钾玻璃组分
	斯琴毕力格 ; 李青会 ; 干福熹
刊名	分析化学
	2013
卷号	41 期号:9 页码:1328
其他题名	Analysis of Some Chinese Potash Glass by Laser Ablation-Inductively Coupled Plasma-Atomic Emission Spectrometry and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry
通讯作者	Li, QH (reprint author), Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China.
中文摘要	利用激光剥蚀电感耦合等离子体原子发射光谱(LA-ICP-AES)和激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)分析了一批中国古代钾玻璃。样品表面磨去100mum以上,并通过预剥蚀去除风化影响,设计剥蚀路径以消除元素分布不均匀影响。通过钙铝及其它微量元素将钾玻璃分成3个亚类,它们可能有不同的配方及制造中心;研究发现,钾玻璃着色剂类型多样化,有单质Cu,Mn~(2+),Cu~(2+),Co~(2+)等;系统研究了钾玻璃的稀土元素特征,成功区分了九只岭地区及风门岭地区的钾玻璃;对两种方法在古代玻璃分析中的特点进行了探讨。
英文摘要	Laser ablation-inductively coupled plasma-atomic emission spectrometry (LA-ICP-AES) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) were applied to analyze ancient Chinese potash glass. The surfaces of glasses were polished over 100 mu m, then pre-ablation was performed to avoid surface weathering effect, and laser ablation was performed in the designed route to eliminate influence of heterogeneity. The glasses were classified into three subgroups by their lime and alumina concentrations, and they may have different recipe and production center. There are various colorants in these glass including metallic copper, and ions of manganese, copper and cobalt. The characteristics of rare earth elements of Chinese potash glass were studied for the first time and it was successfully used to separate the potash glass of Fengmenling and Jiuzhiling. The features of two methods in the studies of ancient glass were discussed.
收录类别	SCI
语种	英语
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.siom.ac.cn/handle/181231/14916]
专题	上海光学精密机械研究所_高密度光存储技术实验室
作者单位	1.[Siqin, Bilige 2.Li Qing-Hui 3.Gan Fu-Xi] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China 4.[Gan Fu-Xi] Fudan Univ, Shanghai 200433, Peoples R China
推荐引用方式 GB/T 7714	斯琴毕力格,李青会,干福熹. 激光剥蚀-电感耦合等离子体-原子发射光谱/质谱法分析中国古代钾玻璃组分[J]. 分析化学,2013,41(9):1328.
APA	斯琴毕力格,李青会,&干福熹.(2013).激光剥蚀-电感耦合等离子体-原子发射光谱/质谱法分析中国古代钾玻璃组分.分析化学,41(9),1328.
MLA	斯琴毕力格,et al."激光剥蚀-电感耦合等离子体-原子发射光谱/质谱法分析中国古代钾玻璃组分".分析化学 41.9(2013):1328.