A novel D2EHPA-based synergistic extraction system for the recovery of chromium (III)
Zhang, Guozhi1,2,3; Chen, Desheng1,2; Zhao, Wei1,2; Zhao, Hongxin1,2; Wang, Lina1,2; Wang, Weijing1,2; Qi, Tao1,2
刊名CHEMICAL ENGINEERING JOURNAL
2016-10-15
卷号302期号:NOV页码:233-238
关键词Synergistic solvent extraction Chromium Di (2-ethylhexyl) phosphoric acid (D2EHPA) Isooctanol Mechanism
ISSN号1385-8947
英文摘要

A synergistic solvent extraction method for recovering chromium (III) was proposed using the mixed extractant consisting of di (2-ethylhexyl) phosphoric acid (D2EHPA) and isooctanol. Based on the synergistic effect and the price of extractant, isooctanol was selected as the effective synergistic extractant in the D2EHPA-based extraction system. The chromium (III) extraction was found to increase and then decrease with increasing isooctanol concentration. The effects of D2EHPA concentration, initial pH, contact time, temperature, and anions concentration on the synergistic extraction of chromium (III) were investigated. The comparative study on the stripping of chromium from the loaded D2EHPA-isooctanol and the loaded D2EHPA was carried out. Based on the experiment results and the analysis of UV-vis and FT-IR spectra, the mechanism on the synergistic extraction of chromium (HI) by D2EHPA-isooctanol mixed extractant was discussed. (C) 2016 Elsevier B.V. All rights reserved.

WOS标题词Science & Technology ; Technology
类目[WOS]Engineering, Environmental ; Engineering, Chemical
研究领域[WOS]Engineering
关键词[WOS]EMULSION LIQUID-MEMBRANE ; AQUEOUS-SOLUTIONS ; WASTE-WATER ; SOLVENT-EXTRACTION ; ACTIVATED-SLUDGE ; REMOVAL ; EQUILIBRIUM ; REDUCTION ; KINETICS ; CR(III)
收录类别SCI
语种英语
WOS记录号WOS:000382590900025
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/21461]  
专题过程工程研究所_湿法冶金清洁生产技术国家工程实验室
作者单位1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Guozhi,Chen, Desheng,Zhao, Wei,et al. A novel D2EHPA-based synergistic extraction system for the recovery of chromium (III)[J]. CHEMICAL ENGINEERING JOURNAL,2016,302(NOV):233-238.
APA Zhang, Guozhi.,Chen, Desheng.,Zhao, Wei.,Zhao, Hongxin.,Wang, Lina.,...&Qi, Tao.(2016).A novel D2EHPA-based synergistic extraction system for the recovery of chromium (III).CHEMICAL ENGINEERING JOURNAL,302(NOV),233-238.
MLA Zhang, Guozhi,et al."A novel D2EHPA-based synergistic extraction system for the recovery of chromium (III)".CHEMICAL ENGINEERING JOURNAL 302.NOV(2016):233-238.
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