Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks

CORC > 长春光学精密机械与物理研究所 > 中国科学院长春光学精密机械与物理研究所 > 中科院长春光机所知识产出

	Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks
	Xiao, L. N.; L. M. Wang; X. N. Shan; H. Y. Guo; L. W. Fu; Y. Y. Hu; X. B. Cui; K. C. Li and J. Q. Xu
刊名	Crystengcomm
	2015
卷号	17 期号:6 页码:1336-1347
英文摘要	Four new organic-inorganic hybrid compounds, namely, [Cu3(4,4'-bpy)3][HSiW12O40]center dot(C3H4N2) (1), [Cu-3(4,4'-bpy)(3)][PMo12O40]center dot(C5H6N2)center dot 0.5H(2)O (2), [Cu-2(4,4'-bpy)(2)][HPMo12O40]center dot(C5H6N2) (3) and [Cu(Phen)(4,4'-bpy)(H2O)](2)[PW12O40]center dot(4,4'-bpy) (4) (C3H4N2 = imidazole, C5H6N2 = 2-aminopyridine, bpy = bipyridine, Phen = 1,10-phenanthroline), have been synthesized and characterized by IR, UV-vis, powder XRD, cyclic voltammetry analysis, photoluminescence analysis, elemental analyses and single crystal X-ray diffraction. The four compounds represent new examples of secondary organic moiety templated frameworks constructed from Keggin polyanions, metal ions and organic ligands. Compounds 1 and 2 present 3-D framework structures; compound 3 exhibits a 1-D ladder-like structure and compound 4 shows a 2-D layered framework structure. It is noted that the packing structures of compounds 1 and 2 are almost identical; however, the crystal space groups and cell parameters of the two are thoroughly different. Such a phenomenon has also been observed between compound 3 and a compound recently reported by us. Compound 4 is the first framework structure constructed from polyoxometalates, metal ions and mixed organic ligands. In addition, all the four frameworks are combined with dissociated organic moieties as templates.
收录类别	SCI
内容类型	期刊论文
源URL	[http://ir.ciomp.ac.cn/handle/181722/55484]
专题	长春光学精密机械与物理研究所_中科院长春光机所知识产出
推荐引用方式 GB/T 7714	Xiao, L. N.,L. M. Wang,X. N. Shan,et al. Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks[J]. Crystengcomm,2015,17(6):1336-1347.
APA	Xiao, L. N..,L. M. Wang.,X. N. Shan.,H. Y. Guo.,L. W. Fu.,...&K. C. Li and J. Q. Xu.(2015).Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks.Crystengcomm,17(6),1336-1347.
MLA	Xiao, L. N.,et al."Secondary organic moiety templated organic-inorganic polyoxometalate-based frameworks".Crystengcomm 17.6(2015):1336-1347.