An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton

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	An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton
	Wang, Jun-Jiao 1; Zhou, An-Xi 1; Wang, Gang-Wei 1; Yang SD(杨尚东)1,2
刊名	Advanced Synthesis and Catalysis
	2014
卷号	356 期号:16 页码:3356-3362
关键词	N-acyliminium ions aluminum triflate dearomatization Mannich-like cyclization
ISSN号	1615-4150
通讯作者	杨尚东
英文摘要	An aluminum triflate-catalyzed intramolecular reaction sequence involving protonation and Mannich-like nucleophilic addition of indoles toward the concise construction of the tetrahydropyrido[1,2-a]indol-6-one skeleton is reported. This new reaction pattern employs a carbon atom as nucleophile to form a CC bond which bears one or even two quaternary carbons and leads to the dearomatization of indoles with high atom economy.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the NSFC (No. 21272100);Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07)
语种	英语
WOS记录号	WOS:000344546600013
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/20707]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,et al. An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton[J]. Advanced Synthesis and Catalysis,2014,356(16):3356-3362.
APA	Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,&Yang SD.(2014).An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton.Advanced Synthesis and Catalysis,356(16),3356-3362.
MLA	Wang, Jun-Jiao,et al."An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton".Advanced Synthesis and Catalysis 356.16(2014):3356-3362.