Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides | |
Tang, Yujie1; Zeng, Yanning2; Hu, Qingxia1; Huang, Fang1,2; Jin, Liqun1; Mo WM(莫卫民)1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Hu XQ(胡信全)1,3 | |
刊名 | Advanced Synthesis and Catalysis
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2016 | |
卷号 | 358期号:16页码:2642-2651 |
关键词 | Iminopyridyl complexes Palladium Heck reaction Suzuki reaction |
ISSN号 | 1615-4150 |
通讯作者 | Jin, Liqun ; 胡信全 ; 孙文华 |
英文摘要 | A series of geometry-constrained iminopyridyl-palladium chlorides were synthesized and characterized. These phosphine-free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross-coupling reactions, achieving turnover numbers as high as 106 towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | the National Natural Science Foundation of China (21473160;21376224);Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province, China |
语种 | 英语 |
WOS记录号 | WOS:000382971300010 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/20684] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast and Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Tang, Yujie,Zeng, Yanning,Hu, Qingxia,et al. Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides[J]. Advanced Synthesis and Catalysis,2016,358(16):2642-2651. |
APA | Tang, Yujie.,Zeng, Yanning.,Hu, Qingxia.,Huang, Fang.,Jin, Liqun.,...&Sun WH.(2016).Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides.Advanced Synthesis and Catalysis,358(16),2642-2651. |
MLA | Tang, Yujie,et al."Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides".Advanced Synthesis and Catalysis 358.16(2016):2642-2651. |
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