Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides
Tang, Yujie1; Zeng, Yanning2; Hu, Qingxia1; Huang, Fang1,2; Jin, Liqun1; Mo WM(莫卫民)1; Sun N(孙楠)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Hu XQ(胡信全)1,3
刊名Advanced Synthesis and Catalysis
2016
卷号358期号:16页码:2642-2651
关键词Iminopyridyl complexes Palladium Heck reaction Suzuki reaction
ISSN号1615-4150
通讯作者Jin, Liqun ; 胡信全 ; 孙文华
英文摘要

A series of geometry-constrained iminopyridyl-palladium chlorides were synthesized and characterized. These phosphine-free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross-coupling reactions, achieving turnover numbers as high as 106 towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the National Natural Science Foundation of China (21473160;21376224);Zhejiang University of Technology and Qianjiang Scholar Program funded by Zhejiang Province, China
语种英语
WOS记录号WOS:000382971300010
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/20684]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast and Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Tang, Yujie,Zeng, Yanning,Hu, Qingxia,et al. Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides[J]. Advanced Synthesis and Catalysis,2016,358(16):2642-2651.
APA Tang, Yujie.,Zeng, Yanning.,Hu, Qingxia.,Huang, Fang.,Jin, Liqun.,...&Sun WH.(2016).Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides.Advanced Synthesis and Catalysis,358(16),2642-2651.
MLA Tang, Yujie,et al."Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides".Advanced Synthesis and Catalysis 358.16(2016):2642-2651.
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