Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature

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	Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature
	Zhao, Hanging 1; Sun W(孙伟)2 ; Miao CX(苗成霞)2 ; Zhao, Quanyi 1
刊名	Journal of Molecular Catalysis A: Chemical
	2014
卷号	393 页码:62-67
关键词	N-hydroxyphthalimide Secondary alcohols Aerobic oxidation Iron salts
ISSN号	1381-1169
通讯作者	苗成霞 ; Zhao, Quanyi
英文摘要	Aerobic oxidation of various alcohols has been accomplished by using a novel catalytic system, N-hydroxyphthalimide (NHPI) combined with Fe(NO₃)₃·9H₂O. Secondary alcohols, especially benzylic and aliphatic alcohols, were smoothly transformed into corresponding ketones with up to 92% yields at room temperature under one atmosphere pressure of oxygen. The influences of reaction conditions such as solvent, different metal catalyst, catalyst loading and the structure of alcohols on the promotion effect were studied. And a possible radical mechanism for the oxidation of secondary alcohols in Fe(NO₃)₃·9H₂O/NHPI/O₂ system was proposed.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (21103207;21133011)
语种	英语
WOS记录号	WOS:000341462700008
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/20317]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Hanging,Sun W,Miao CX,et al. Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature[J]. Journal of Molecular Catalysis A: Chemical,2014,393:62-67.
APA	Zhao, Hanging,Sun W,Miao CX,&Zhao, Quanyi.(2014).Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature.Journal of Molecular Catalysis A: Chemical,393,62-67.
MLA	Zhao, Hanging,et al."Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature".Journal of Molecular Catalysis A: Chemical 393(2014):62-67.