AgNO3 as nitrogen source for rhodium(III)-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes | |
Li JX(李纪兴)1,2; Zhou H(周慧)1,2; Zhang JL(张金龙)1; Yang HM(杨化萌)1; Jiang GX(蒋高喜)1 | |
刊名 | Chemical Communications
![]() |
2016 | |
卷号 | 52期号:61页码:9589-9592 |
ISSN号 | 1359-7345 |
通讯作者 | 蒋高喜 |
英文摘要 | A new approach has been established for Rh(III)-catalyzed direct aza oxidative cyclization of non-prefunctionalized azobenzenes to provide 2-aryl-2H-benzotriazoles in good yields, in which AgNO3 instead of conventional azide reagents for the first time functions as the nitrogen source for the nitrogenation reaction. Preliminary mechanistic studies suggest that the Rh(III)-catalyst could account for the nitration reaction, and subsequently cationic silver species might both play a vital role in the fission of the nitrogen–oxygen bonds in nitro groups and promote aza oxidative cyclization. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | Hundred Talent Program of Chinese Academy of Sciences (CAS) |
语种 | 英语 |
WOS记录号 | WOS:000380324300023 |
内容类型 | 期刊论文 |
源URL | [http://210.77.64.217/handle/362003/20246] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 兰州化学物理研究所_苏州研究院 |
作者单位 | 1.Chinese Acad Sci, LICP, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Li JX,Zhou H,Zhang JL,et al. AgNO3 as nitrogen source for rhodium(III)-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes[J]. Chemical Communications,2016,52(61):9589-9592. |
APA | Li JX,Zhou H,Zhang JL,Yang HM,&Jiang GX.(2016).AgNO3 as nitrogen source for rhodium(III)-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes.Chemical Communications,52(61),9589-9592. |
MLA | Li JX,et al."AgNO3 as nitrogen source for rhodium(III)-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes".Chemical Communications 52.61(2016):9589-9592. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论