Electronic metal-support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts
Ma ZW(马占伟)1,2; Xiong XM(熊绪茂)1; Song CL(宋承立)1; Hu B(胡斌)1; Zhang, Weiqiang3
刊名RSC Advances
2016
卷号6期号:56页码:51106-51110
ISSN号2046-2069
通讯作者胡斌
英文摘要

Here we report that the electronic metal–support interaction influences the catalytic activity of ammonia synthesis. This effect produces an upwards shift of the d-band center of Ru nanoparticles. The upward shift of the d-band center of the Ru nanoparticles is considered to enhance the dissociation of the N2 molecule.

学科主题物理化学与绿色催化
收录类别SCI
资助信息National Natural Science Foundation of China (Grant No. 21403257)
语种英语
WOS记录号WOS:000377515200079
内容类型期刊论文
源URL[http://210.77.64.217/handle/362003/19977]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Changchun Zhongke Haorong New Mat Res Co Ltd, Changchun 130000, Peoples R China
推荐引用方式
GB/T 7714
Ma ZW,Xiong XM,Song CL,et al. Electronic metal-support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts[J]. RSC Advances,2016,6(56):51106-51110.
APA Ma ZW,Xiong XM,Song CL,Hu B,&Zhang, Weiqiang.(2016).Electronic metal-support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts.RSC Advances,6(56),51106-51110.
MLA Ma ZW,et al."Electronic metal-support interactions enhance the ammonia synthesis activity over ruthenium supported on Zr-modified CeO2 catalysts".RSC Advances 6.56(2016):51106-51110.
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