Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 仿生能源与储能系统团队

	Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries
	Ma, Jun 1; Hu, Pu 1; Cui, Guanglei 1; Chen, Liquan 1,2
刊名	CHEMISTRY OF MATERIALS
	2016-06-14
卷号	28 期号:11 页码:3578-3606
英文摘要	Spinel LiNi0.5Mn1.5O4 with high operating voltage (similar to 4.7 V vs Li/Li+), high theoretical capacity of 148 mAh g(-1), fast lithium ion diffusion kinetics, and potentially low cost is the most potential candidate material for high energy density LIBs used in plug-in hybrid electric vehicles and pure electric vehicles. However, the high operating voltage of LiNi0.5Mn1.5O4 challenges the electrochemical stability of other components in the batteries and induce diverse interfacial side reactions, leading to irreversible capacity loss, poor cycling performance, and safety issues, especially at the elevated temperatures. Thus, a basic understanding of the intrinsic surface properties of LiNi0.5Mn1.5O4 and the mechanism of interfacial interactions between each component in the electrochemical system is a critical requirement for developing substantial enhancements of LiNi0.5Mn1.5O4-based batteries. In this review, we summarize the surface/interface reactions and challenges in the whole cell system of LiNi0.5Mn1.5O4-based LIBs. Perspectives and strategies for LiNi0.5Mn1.5O4-based high energy density batteries used in PHEV/EVs are also proposed at last.
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]	Chemistry ; Materials Science
关键词[WOS]	HIGH-VOLTAGE SPINEL ; GEL POLYMER ELECTROLYTE ; ALKYLCARBONATE-BASED ELECTROLYTES ; HIGH-TEMPERATURE PERFORMANCE ; SULFONE-BASED ELECTROLYTES ; RECHARGEABLE LI BATTERIES ; CHARGE-DISCHARGE BEHAVIOR ; HIGH-RATE CAPABILITY ; LONG-CYCLE-LIFE ; 5 V CATHODE
收录类别	SCI
语种	英语
WOS记录号	WOS:000378016400005
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn/handle/337004/8325]
专题	青岛生物能源与过程研究所_仿生能源与储能系统团队
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioprocess Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Phys, Key Lab Renewable Energy, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Ma, Jun,Hu, Pu,Cui, Guanglei,et al. Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries[J]. CHEMISTRY OF MATERIALS,2016,28(11):3578-3606.
APA	Ma, Jun,Hu, Pu,Cui, Guanglei,&Chen, Liquan.(2016).Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries.CHEMISTRY OF MATERIALS,28(11),3578-3606.
MLA	Ma, Jun,et al."Surface and Interface Issues in Spinel LiNi0.5Mn1.5O4: Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries".CHEMISTRY OF MATERIALS 28.11(2016):3578-3606.