Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization
	Chen, Dong 1,2; Xu, Wen-Dan 1,2; Liu, Hao-Miao 1,2; Li, Ming-Ming 3; Yan, Yong-Min 1; Li, Xiao-Nian 1; Li, Yan1 ; Cheng, Yong-Xian 1; Qin, Hong-Bo1
刊名	CHEMICAL COMMUNICATIONS
	2016
卷号	52 期号:55 页码:8561-8564
英文摘要	Enantioselective total synthesis of (+)-Lingzhiol has been achieved. It is the first example of in tandem semipinacol rearrangement reactions, the migrated aryl group further reacting with the carbonyl oxonium electrophile to furnish a polycyclic skeleton. Our synthesis involves 13 steps and proceeds in 6% overall yield.
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	QUATERNARY CARBON STEREOCENTERS ; FORMAL TOTAL-SYNTHESIS ; (+/-)-WELWITINDOLINONE-A ISONITRILE ; PINACOL REARRANGEMENT ; DASYSCYPHUS-NIVEUS ; CONSTRUCTION ; STRATEGY ; (+/-)-LINGZHIOL ; DITERPENOIDS ; ALKALOIDS
收录类别	SCI
语种	英语
WOS记录号	WOS:000379483200015
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/28479]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Photochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Yunnan Baiyao Grp Corp Ltd, Kunming 650032, Peoples R China
推荐引用方式 GB/T 7714	Chen, Dong,Xu, Wen-Dan,Liu, Hao-Miao,et al. Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization[J]. CHEMICAL COMMUNICATIONS,2016,52(55):8561-8564.
APA	Chen, Dong.,Xu, Wen-Dan.,Liu, Hao-Miao.,Li, Ming-Ming.,Yan, Yong-Min.,...&Qin, Hong-Bo.(2016).Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization.CHEMICAL COMMUNICATIONS,52(55),8561-8564.
MLA	Chen, Dong,et al."Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization".CHEMICAL COMMUNICATIONS 52.55(2016):8561-8564.