Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization | |
Chen, Dong1,2; Xu, Wen-Dan1,2; Liu, Hao-Miao1,2; Li, Ming-Ming3; Yan, Yong-Min1; Li, Xiao-Nian1; Li, Yan1![]() ![]() | |
刊名 | CHEMICAL COMMUNICATIONS
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2016 | |
卷号 | 52期号:55页码:8561-8564 |
英文摘要 | Enantioselective total synthesis of (+)-Lingzhiol has been achieved. It is the first example of in tandem semipinacol rearrangement reactions, the migrated aryl group further reacting with the carbonyl oxonium electrophile to furnish a polycyclic skeleton. Our synthesis involves 13 steps and proceeds in 6% overall yield. |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | QUATERNARY CARBON STEREOCENTERS ; FORMAL TOTAL-SYNTHESIS ; (+/-)-WELWITINDOLINONE-A ISONITRILE ; PINACOL REARRANGEMENT ; DASYSCYPHUS-NIVEUS ; CONSTRUCTION ; STRATEGY ; (+/-)-LINGZHIOL ; DITERPENOIDS ; ALKALOIDS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000379483200015 |
内容类型 | 期刊论文 |
源URL | [http://ir.kib.ac.cn/handle/151853/28479] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Photochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Yunnan Baiyao Grp Corp Ltd, Kunming 650032, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Dong,Xu, Wen-Dan,Liu, Hao-Miao,et al. Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization[J]. CHEMICAL COMMUNICATIONS,2016,52(55):8561-8564. |
APA | Chen, Dong.,Xu, Wen-Dan.,Liu, Hao-Miao.,Li, Ming-Ming.,Yan, Yong-Min.,...&Qin, Hong-Bo.(2016).Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization.CHEMICAL COMMUNICATIONS,52(55),8561-8564. |
MLA | Chen, Dong,et al."Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel- Crafts type cyclization".CHEMICAL COMMUNICATIONS 52.55(2016):8561-8564. |
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