Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H

CORC > 昆明植物研究所 > 中国科学院昆明植物研究所 > 植物化学与西部植物资源持续利用国家重点实验室

	Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H
	Pan, Zhiqiang 1; Qin, Xu-Jie1 ; Liu, Ya-Ping 1; Wu, Ting 1,2; Luo, Xiao-Dong1 ; Xie, Chengfeng 1
刊名	ORGANIC LETTERS
	2016-02-19
卷号	18 期号:4 页码:654-657
英文摘要	Alstoscholarisines H-J (1-3), new monoterpenoid indole alkaloids with an unprecedented skeleton created via the formation of a C-3/N-1 bond, were isolated from Alstonia scholaris. Their structures were established by extensive spectroscopic analyses and the assessment of single-crystal X-ray diffraction data. The total synthesis of alstoscholarisine H was achieved via the regioselective nucleophilic addition of pyridinium through a bioinspired iminium ion intermediate followed by Pictet-Spengler-like cyclization.
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	FLIGHT MASS-SPECTROMETRY ; AKUAMMILINE ALKALOIDS ; MELODININE E ; SALTS ; LEAVES ; (+)-SCHOLARISINE ; CONSTRUCTION ; 1,4-DIHYDROPYRIDINES ; (-)-LEUCONOXINE ; IDENTIFICATION
收录类别	SCI
语种	英语
WOS记录号	WOS:000370768200007
内容类型	期刊论文
源URL	[http://ir.kib.ac.cn/handle/151853/25987]
专题	昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室
作者单位	1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Pan, Zhiqiang,Qin, Xu-Jie,Liu, Ya-Ping,et al. Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H[J]. ORGANIC LETTERS,2016,18(4):654-657.
APA	Pan, Zhiqiang,Qin, Xu-Jie,Liu, Ya-Ping,Wu, Ting,Luo, Xiao-Dong,&Xie, Chengfeng.(2016).Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H.ORGANIC LETTERS,18(4),654-657.
MLA	Pan, Zhiqiang,et al."Alstoscholarisines H-J, Indole Alkaloids from Alstonia scholaris: Structural Evaluation and Bioinspired Synthesis of Alstoscholarisine H".ORGANIC LETTERS 18.4(2016):654-657.