Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin

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	Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin
	Zhao S(赵帅); Liu C(刘超); Guo Y(郭勇); Xiao JC(肖吉昌); Chen QY(陈庆云)
刊名	J. Org. Chem.
	2014
卷号	79 期号:18 页码:8926-8931
其他题名	空气中β-四三氟甲基-meso-四苯基钴卟啉催化苄胺氧化偶联为亚胺
通讯作者	陈庆云
英文摘要	Oxidative coupling of benzylamines to imines by molecular oxygen is efficiently realized in the presence of very low catalyst loadings of Co(II) beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin. Due to the effect of four beta-CF3 groups, the catalyst shows good selectivity and very high turnover number. The reaction is easily scaled up and may provide a convenient way to prepare many imines in large scale.
学科主题	氟化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/jo5017212
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/38808]
专题	上海有机化学研究所_中科院有机氟化学重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Zhao S,Liu C,Guo Y,et al. Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin[J]. J. Org. Chem.,2014,79(18):8926-8931.
APA	赵帅,刘超,郭勇,肖吉昌,&陈庆云.(2014).Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin.J. Org. Chem.,79(18),8926-8931.
MLA	赵帅,et al."Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin".J. Org. Chem. 79.18(2014):8926-8931.