Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach | |
Chen GQ(陈根强); Zhang XN(张肖楠); Wei Y(魏音); Tang XY(唐翔鹰); Shi M(施敏) | |
刊名 | Angew. Chem.-Int. Edit.
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2014 | |
卷号 | 53期号:32页码:8492-8497 |
其他题名 | 催化剂导向的吡咯合成 |
通讯作者 | 施敏 |
英文摘要 | A novel Ru-0- and Rh-I-catalyzed noncarbonylative and carbonylative cycloisomerization of readily available 3-alkynyl imine derivatives has been developed to provide 3,4-fused or nonfused pyrrole derivatives efficiently in moderate to excellent yields. The key steps involve the formation of a ruthenium carbenoid intermediate or a rhodacycle intermediate, respectively. In these reactions, CO can serve as a ligand or a reagent. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1002/anie.201405215 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39093] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Chen GQ,Zhang XN,Wei Y,et al. Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach[J]. Angew. Chem.-Int. Edit.,2014,53(32):8492-8497. |
APA | 陈根强,张肖楠,魏音,唐翔鹰,&施敏.(2014).Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach.Angew. Chem.-Int. Edit.,53(32),8492-8497. |
MLA | 陈根强,et al."Catalyst-Dependent Divergent Synthesis of Pyrroles from 3-Alkynyl Imine Derivatives: A Noncarbonylative and Carbonylative Approach".Angew. Chem.-Int. Edit. 53.32(2014):8492-8497. |
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