Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction
	Wu SY(吴生英)1; Tang J(唐俊)1; Han JW(韩建伟)1; Mao D(毛丹)1; Liu X(刘欣)1; Gao S(高省)1; Yu JJ(余建军)1; Wang LM(王利民)1
刊名	Tetrahedron
	2014
卷号	70 期号:35 页码:5986-5992
其他题名	设计合成新的salen配体及其钴和镱络合物: 作为催化剂催化不对称henry反应, 并致使其产物的不对称反转效应
通讯作者	韩建伟 ; 王利民
英文摘要	Reversal of enantioselectivity in asymmetric Henry reactions was achieved with novel chiral C-2-symmetric salen ligands bearing morpholine moieties by changing the Lewis acid center from Co(II) to Yb(III). The possible transition state models were supported by mass spectrometry experiments. (C) 2014 Elsevier Ltd. All rights reserved.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1016/j.tet.2014.05.085
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39090]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.华东理工大学 2.中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Wu SY,Tang J,Han JW,et al. Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction[J]. Tetrahedron,2014,70(35):5986-5992.
APA	吴生英.,唐俊.,韩建伟.,毛丹.,刘欣.,...&王利民.(2014).Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction.Tetrahedron,70(35),5986-5992.
MLA	吴生英,et al."Design of C2-symmetric salen ligands and their Co(II)- or Yb(III)-complexes, and their role in the reversal of enantioselectivity in the asymmetric Henry reaction".Tetrahedron 70.35(2014):5986-5992.