Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution

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	Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution
	Gao DW(高得伟); Gu Q(顾庆); You SL(游书力)
刊名	ACS Catal.
	2014
卷号	4 期号:8 页码:2741-2745
其他题名	钯(II)催化的分子间C-H键直接碘化: 通过动力学拆分合成轴手性化合物的一种有效方法
通讯作者	顾庆 ; 游书力
英文摘要	An efficient protocol to synthesize axially chiral compounds via kinetic resolution by Pd(II)-catalyzed direct C H iodination was realized (up to s = 27). The iodide product could be easily transformed to aryl-substituted pyridine N-oxides via the Suzuki Miyaura coupling, which proved to be a suitable catalyst in asymmetric allylation of benzaldehyde with allyltrichlorosilane.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/cs500813z
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39084]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Gao DW,Gu Q,You SL. Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution[J]. ACS Catal.,2014,4(8):2741-2745.
APA	高得伟,顾庆,&游书力.(2014).Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution.ACS Catal.,4(8),2741-2745.
MLA	高得伟,et al."Pd(II)-Catalyzed Intermolecular Direct C-H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution".ACS Catal. 4.8(2014):2741-2745.