Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates

CORC > 上海有机化学研究所 > 中国科学院上海有机化学研究所 > 金属有机化学国家重点实验室

	Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates
	Lai ZW(赖增伟)1; Yang RF(杨荣飞)1; Ye KY(叶克印)1; SUN HONGBIN 1; You SL(游书力)1
刊名	Beilstein J. Org. Chem.
	2014
卷号	10 页码:1261-1266
其他题名	1-双(三氟甲基)膦基-1'-恶唑啉二茂铁配体的合成和它们在钯催化的单取代烯丙基底物的区域选择性以及对映选择性烯丙基烷基化中的应用
通讯作者	SUN HONGBIN ; 游书力
英文摘要	A class of novel, easily accessible and air-stable 1-[bis(trifluoromethyl)phosphine]-1'-oxazolinylferrocene ligands has been synthesized from ferrocene. It became apparent that these ligands can be used in the regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates in a highly efficient manner. Excellent regio- and enantioselectivity could be obtained for a wide range of substrates.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.3762/bjoc.10.126
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39068]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	1.中科院上海有机化学研究所 2.中国药科大学 3.康龙化成(北京)新药技术有限公司
推荐引用方式 GB/T 7714	Lai ZW,Yang RF,Ye KY,et al. Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates[J]. Beilstein J. Org. Chem.,2014,10:1261-1266.
APA	赖增伟,杨荣飞,叶克印,SUN HONGBIN,&游书力.(2014).Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates.Beilstein J. Org. Chem.,10,1261-1266.
MLA	赖增伟,et al."Synthesis of 1-[bis(trifluoromethyl)phosphine]-1 '-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates".Beilstein J. Org. Chem. 10(2014):1261-1266.