Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation

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	Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation
	Gao DW(高得伟); Yin Q(殷勤); Gu Q(顾庆); You SL(游书力)
刊名	J. Am. Chem. Soc.
	2014
卷号	136 期号:13 页码:4841-4844
其他题名	通过钯(0)催化的分子内直接C-H键芳基化对映选择性地构建平面手性二茂铁
通讯作者	顾庆 ; 游书力
英文摘要	A highly efficient synthesis of planar chiral ferrocenes by enantioselective Pd(0)-catalyzed direct C-H arylation from readily available starting materials under mild reaction conditions was developed (up to 99% yield, 99% ee). The products can be easily transformed to the highly efficient planar ferrocene ligands, which have demonstrated high efficiency in Pd-catalyzed asymmetric allylic alkylation and amination reactions.
学科主题	金属有机化学
收录类别	SCI
原文出处	http://dx.doi.org/10.1021/ja500444v
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39052]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Gao DW,Yin Q,Gu Q,et al. Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation[J]. J. Am. Chem. Soc.,2014,136(13):4841-4844.
APA	高得伟,殷勤,顾庆,&游书力.(2014).Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation.J. Am. Chem. Soc.,136(13),4841-4844.
MLA	高得伟,et al."Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C-H Bond Arylation".J. Am. Chem. Soc. 136.13(2014):4841-4844.