Ozonation of Methylenecyclopropanes

	Ozonation of Methylenecyclopropanes
	Sang R(桑睿); Tang XY(唐翔鹰); Shi M(施敏)
刊名	Org. Chem. Front.
	2014
卷号	1 页码:770-773
其他题名	亚甲基环丙烷的臭氧化反应
通讯作者	施敏
英文摘要	Ozonation of methylenecyclopropanes bearing gem-disubstituted electron-withdrawing groups (EWG) gave ring-opened oxidative products in moderate to good yields. For MCPs in which EWGs are two methoxycarbonyl groups, the ozonation gave oxidative cyclization products in methanol at ?78 °C in the presence of CuCl; for MCPs in which EWGs are one methoxycarbonyl and one trifluoromethyl group, the ozonation produced α-diketones in ethyl acetate (EA) at ?78 °C.
学科主题	金属有机化学
原文出处	http://dx.doi.org/10.1039/c4qo00160e
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39027]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Sang R,Tang XY,Shi M. Ozonation of Methylenecyclopropanes[J]. Org. Chem. Front.,2014,1:770-773.
APA	桑睿,唐翔鹰,&施敏.(2014).Ozonation of Methylenecyclopropanes.Org. Chem. Front.,1,770-773.
MLA	桑睿,et al."Ozonation of Methylenecyclopropanes".Org. Chem. Front. 1(2014):770-773.