Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins

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	Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins
	Li XH(李小惠); Fang P(方萍); Chen D(陈娣); Hou XL(侯雪龙)
刊名	Org. Chem. Front.
	2014
卷号	1 页码:969-973
其他题名	钯催化烯丙基取代反应对4-取代-3,4-二氢苯并吡喃酮的动力学拆分: 反式-3,4-二取代-3,4-二氢苯并吡喃酮的对映选择性合成
通讯作者	侯雪龙
英文摘要	The kinetic resolution of 4-substituted-3,4-dihydrocoumarins was realized via Pd-catalyzed allylic substitution reaction using Trost’s chiral ligand L12, affording optically active mono- and trans-3,4-disubstituted dihydrocoumarin derivatives in high yields and with high enantioselectivities with an S factor up to 55.
学科主题	金属有机化学
原文出处	http://dx.doi.org/10.1039/c4qo00178h
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39009]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Li XH,Fang P,Chen D,et al. Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins[J]. Org. Chem. Front.,2014,1:969-973.
APA	李小惠,方萍,陈娣,&侯雪龙.(2014).Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins.Org. Chem. Front.,1,969-973.
MLA	李小惠,et al."Kinetic Resolution of 4-Substituted-3,4-dihydrocoumarins via Pd-Catalyzed Asymmetric Allylic Alkylation Reaction: Enantioselective Synthesis of trans 3,4-Disubstituted -3,4-dihydrocoumarins".Org. Chem. Front. 1(2014):969-973.