Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds

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	Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds
	Li C(李春); Li WX(李伟逊); Xu S(许胜); Duan WL(段伟良)
刊名	Org. Chem. Front.
	2014
卷号	1 页码:541-545
其他题名	钯催化二取代膦氢对不饱和羰基化合物的1.4加成缺电子烯烃: 合成含膦手性和碳手性的膦化合物
通讯作者	段伟良
英文摘要	Highly stereoselective 1,4-addition of alkylphenylphosphines to α,β-unsaturated carbonyl compounds catalyzed by PCP or NCN pincer–Pd complexes is described to synthesize chiral phosphorus compounds earing both P- and C-stereogenic centers with good to excellent enantioselectivity (up to 99.6% ee).
学科主题	金属有机化学
原文出处	http://dx.doi.org/10.1039/c4qo00017j
语种	英语
内容类型	期刊论文
源URL	[http://ir.sioc.ac.cn/handle/331003/39004]
专题	上海有机化学研究所_金属有机化学国家重点实验室
作者单位	中科院上海有机化学研究所
推荐引用方式 GB/T 7714	Li C,Li WX,Xu S,et al. Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds[J]. Org. Chem. Front.,2014,1:541-545.
APA	李春,李伟逊,许胜,&段伟良.(2014).Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds.Org. Chem. Front.,1,541-545.
MLA	李春,et al."Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds".Org. Chem. Front. 1(2014):541-545.