Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds | |
Li C(李春); Li WX(李伟逊); Xu S(许胜); Duan WL(段伟良) | |
刊名 | Org. Chem. Front.
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2014 | |
卷号 | 1页码:541-545 |
其他题名 | 钯催化二取代膦氢对不饱和羰基化合物的1.4加成缺电子烯烃: 合成含膦手性和碳手性的膦化合物 |
通讯作者 | 段伟良 |
英文摘要 | Highly stereoselective 1,4-addition of alkylphenylphosphines to α,β-unsaturated carbonyl compounds catalyzed by PCP or NCN pincer–Pd complexes is described to synthesize chiral phosphorus compounds earing both P- and C-stereogenic centers with good to excellent enantioselectivity (up to 99.6% ee). |
学科主题 | 金属有机化学 |
原文出处 | http://dx.doi.org/10.1039/c4qo00017j |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.sioc.ac.cn/handle/331003/39004] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
作者单位 | 中科院上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Li C,Li WX,Xu S,et al. Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds[J]. Org. Chem. Front.,2014,1:541-545. |
APA | 李春,李伟逊,许胜,&段伟良.(2014).Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds.Org. Chem. Front.,1,541-545. |
MLA | 李春,et al."Palladium-catalyzed 1,4-addition of secondary alkylphenylphosphines to α,β-unsaturated carbonyl compounds for the synthesis of phosphorus- and carbon-stereogenic compounds".Org. Chem. Front. 1(2014):541-545. |
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