Identification of metal-cage coupling in a single metallofullerene by inelastic electron tunneling spectroscopy

	Identification of metal-cage coupling in a single metallofullerene by inelastic electron tunneling spectroscopy
	Jiang, J; Gao B(高斌); Gao, B; Hu, ZP; Lu, W; Wu, ZY; Yang, JL; Luo, Y; Wu ZY(吴自玉)
刊名	APPLIED PHYSICS LETTERS
	2010
卷号	96 期号:25 页码:253110
关键词	density functional theory electron density electron-phonon interactions fullerene compounds tunnelling spectra
通讯作者	[Jiang, J. ; Luo, Y.] Royal Inst Technol, Sch Biotechnol, Dept Theoret Chem, S-10691 Stockholm, Sweden ; [Gao, B. ; Wu, Z. Y.] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China ; [Hu, Z. P. ; Yang, J. L. ; Luo, Y.] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China ; [Lu, Wei] Chinese Acad Sci, Shanghai Inst Tech Phys, Natl Lab Infrared Phys, Shanghai 200083, Peoples R China
英文摘要	We report hybrid density functional theory calculations for inelastic electron tunneling spectroscopy (IETS) of a single metallofullerene Gd@C(82). It is found that the metal atom inside the carbon cage can have significant impact on the IETS spectral profiles of the system, by modulating both the vibration and electron density. It is demonstrated that the IETS signals are very sensitive to the changes in the metal position and charge states, so that provide a unique tool for identifying the metal-cage coupling in metallofullerenes. (C) 2010 American Institute of Physics. [doi:10.1063/1.3455905]
学科主题	Physics
类目[WOS]	Physics, Applied
研究领域[WOS]	Physics
原文出处	SCI
语种	英语
WOS记录号	WOS:000279168100056
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/241053]
专题	高能物理研究所_多学科研究中心高能物理研究所_实验物理中心高能物理研究所_粒子天体物理中心高能物理研究所_理论物理室
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Jiang, J,Gao B,Gao, B,et al. Identification of metal-cage coupling in a single metallofullerene by inelastic electron tunneling spectroscopy[J]. APPLIED PHYSICS LETTERS,2010,96(25):253110.
APA	Jiang, J.,高斌.,Gao, B.,Hu, ZP.,Lu, W.,...&吴自玉.(2010).Identification of metal-cage coupling in a single metallofullerene by inelastic electron tunneling spectroscopy.APPLIED PHYSICS LETTERS,96(25),253110.
MLA	Jiang, J,et al."Identification of metal-cage coupling in a single metallofullerene by inelastic electron tunneling spectroscopy".APPLIED PHYSICS LETTERS 96.25(2010):253110.