Local atomic structure of piperidyl Nd dithiocarbamate

	Local atomic structure of piperidyl Nd dithiocarbamate
	Wu ZH(吴忠华); Guo L(郭林); Ju X(巨新); Hu TD(胡天斗); Wu, ZH; Guo, L; Ju, X; Hu, TD; Li, QS; Zhu, HS
刊名	CHINESE PHYSICS LETTERS
	1999
卷号	16 期号:8 页码:583-585
通讯作者	Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing 100039, Peoples R China ; Beijing Inst Technol, Coll Chem Engn & Mat Sci, Beijing 100081, Peoples R China ; Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
英文摘要	The atomic structure of a novel rare earth complex consisting of Nd and the sulfur-containing ligand pipdte (C5H10NCS2-) has been studied with extended x-ray absorption fine structure (EXAFS) and x-ray diffraction techniques. The complex of formula Nd(pipdtc)(4)N(CH3)(4) crystallizes in the monoclinic space group P2(1)/n with the following lattice parameters, a = 22.685(2), b = 20.332(2), c = 17.1270(10)degrees, beta = 100.570(10)degrees, Z 8. The calculated density is 1.47 g/cm(3) A new derivative method is used to remove the post-edge absorption background including the multielectron excitation effect. The EXAFS results demonstrate that there are about eight S and four O atoms around Nd with the Nd-S bond length of 2.916 Angstrom and the Nd-O bond length of 2.415 Angstrom, respectively. This implies that the powder of this complex is not stable and is easy to oxidize in air. The possible change of structure before and after oxidation is discussed.
学科主题	Physics
类目[WOS]	Physics, Multidisciplinary
研究领域[WOS]	Physics
原文出处	SCI
语种	英语
WOS记录号	WOS:000082288500014
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/238027]
专题	高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Wu ZH,Guo L,Ju X,et al. Local atomic structure of piperidyl Nd dithiocarbamate[J]. CHINESE PHYSICS LETTERS,1999,16(8):583-585.
APA	吴忠华.,郭林.,巨新.,胡天斗.,Wu, ZH.,...&Zhu, HS.(1999).Local atomic structure of piperidyl Nd dithiocarbamate.CHINESE PHYSICS LETTERS,16(8),583-585.
MLA	吴忠华,et al."Local atomic structure of piperidyl Nd dithiocarbamate".CHINESE PHYSICS LETTERS 16.8(1999):583-585.