The electronic structure of hexene on Ru(1010) surface | |
Zhang, JH![]() ![]() ![]() ![]() | |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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2002 | |
卷号 | 18期号:5页码:437-440 |
关键词 | hexene dehydrogenated electronic structure |
其他题名 | 己烯在Ru(1010)表面价带电子特性研究 |
通讯作者 | Zhejiang Univ, Dept Phys, Hangzhou 310027, Peoples R China ; Chinese Acad Sci, Inst High Energy Phys, Lab Synchrotron Radiat, Beijing 10039, Peoples R China |
英文摘要 | The adsorption of hexene(C6H12) on Ru(1010) surface has been studied by the polarized angle-resolved ultra-violet photoemission spectroscope (ARUPS) and X-ray photoemission spectroscope (XPS). The results show that the hexene absorbs in a molecular state on the Ru (10 TO) surface below 200 K, the molecular orbits of pi(CC), sigma(CC) and pi(CH) were found at 7. 5, 9. 4 and 11. 1 eV respectively. The results of the polarized ARUPS show that the sigma(CC) orbit is symmetry about a mirror plane along <1210> azimuth but the pi(CC) orbit is anti-symmetry about a mirror plane. The results suggest that the hexene molecule lies in a plane along <1210> azimuth, With warming the substrate to 200 K the pi(CH) molecular orbit increases 0. 2 eV in binding energy, and the C is core level decreases 0. 3 eV in binding energy, the results suggest that dehydrogenated of hexene occurs at 200 K. |
学科主题 | Chemistry |
类目[WOS] | Chemistry, Physical |
研究领域[WOS] | Chemistry |
原文出处 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000175739600011 |
内容类型 | 期刊论文 |
源URL | [http://ir.ihep.ac.cn/handle/311005/237483] ![]() |
专题 | 高能物理研究所_多学科研究中心 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | Zhang, JH,Zhuang, YY,Wu, Y,et al. The electronic structure of hexene on Ru(1010) surface[J]. ACTA PHYSICO-CHIMICA SINICA,2002,18(5):437-440. |
APA | Zhang, JH.,Zhuang, YY.,Wu, Y.,Bao, SN.,Liu, FQ.,...&钱海杰.(2002).The electronic structure of hexene on Ru(1010) surface.ACTA PHYSICO-CHIMICA SINICA,18(5),437-440. |
MLA | Zhang, JH,et al."The electronic structure of hexene on Ru(1010) surface".ACTA PHYSICO-CHIMICA SINICA 18.5(2002):437-440. |
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