Zinc(II)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature

CORC > 化学研究所 > 中国科学院化学研究所 > 胶体、界面与化学热力学实验室

	Zinc(II)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature
	Hu, Jiayin; Ma, Jun; Zhu, Qinggong; Qian, Qingli; Han, Hongling; Mei, Qingqing; Han, Buxing
刊名	GREEN CHEMISTRY
	2016
卷号	18 期号:2 页码:382-385
英文摘要	Carbon dioxide (CO2) is an abundant and renewable feedstock for the production of value-added chemicals. Herein, we carried out the first work to use ZnI2/NEt3 as the catalyst for the reactions of CO2 and propargylic alcohols to form alpha-alkylidene cyclic carbonates. It was discovered that the catalyst system could efficiently promote the reaction at room temperature under solvent-free conditions, and the yields of the target products could reach 99%. The zinc(II) and NEt3 play excellent synergistic roles in activating both CO2 and propargylic alcohols.
收录类别	SCI
语种	英语
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/33829]
专题	化学研究所_胶体、界面与化学热力学实验室
作者单位	Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Hu, Jiayin,Ma, Jun,Zhu, Qinggong,et al. Zinc(II)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature[J]. GREEN CHEMISTRY,2016,18(2):382-385.
APA	Hu, Jiayin.,Ma, Jun.,Zhu, Qinggong.,Qian, Qingli.,Han, Hongling.,...&Han, Buxing.(2016).Zinc(II)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature.GREEN CHEMISTRY,18(2),382-385.
MLA	Hu, Jiayin,et al."Zinc(II)-catalyzed reactions of carbon dioxide and propargylic alcohols to carbonates at room temperature".GREEN CHEMISTRY 18.2(2016):382-385.