Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis

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	Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis
	Li, Yun-Wu ; Ma, Hui-Yan ; Wang, Su-Na ; Xu, Jian ; Li, Da-Cheng ; Dou, Jian-Min ; Bu, Xian-He
刊名	RSC ADVANCES
	2015
卷号	5 期号:108 页码:88809-88815
关键词	METAL-ORGANIC FRAMEWORKS SELECTIVE GAS-ADSORPTION HIGH CO2 UPTAKE DRUG-DELIVERY HYDROTHERMAL SYNTHESIS HYDROGEN STORAGE SPIN-CROSSOVER PORE-SIZE COMPLEXES TOPOLOGY
ISSN号	2046-2069
中文摘要	Three new Zn-II-ditetrazolate coordination polymers (CPs), namely [Zn(m-pdtz)(4,4'-bipy)(H2O)](n) (1), [Zn2Cl2(m-pdtz)(4,4'-bipy)](n) (2) and [Zn-2(OH)(2)(m-pdtz)](n) (3) (4,4'-bipy = 4,4'-bipyridine, m-H(2)pdtz = 5,5'-1,3-phenylene-ditetrazole), have been constructed by an in situ ditetrazolate-ligand synthesis system. The formation of m-pdtz(2-) ligand involves the Sharpless [2 + 3] cycloaddition reaction between isophthalonitrile (IPN) and NaN3 in the presence of Zn2+ ions as Lewis-acid catalysts under hydro/solvothermal conditions. Single-crystal structural analyses reveal that compound 1 exhibits a new 6-connected 3D structural topology constructed from dimeric {Zn-2} clusters as secondary building units (SBUs), compound 2 represents a 2D sql structural feature built from rhombic tetrameric {Zn-4} rings as SBUs, while compound 3 displays a new (4,6)-connected 3D structural topology constructed from rod-shaped 1D Zn-chains as SBUs. Regarding these three CPs, we have performed a thorough investigation on their crystal structure, topology, and fluorescence property.
收录类别	SCI
原文出处	10.1039/c5ra15576b
语种	英语
公开日期	2016-05-12
内容类型	期刊论文
源URL	[http://ir.xtbg.org.cn/handle/353005/9813]
专题	西双版纳热带植物园_文献共享
推荐引用方式 GB/T 7714	Li, Yun-Wu,Ma, Hui-Yan,Wang, Su-Na,et al. Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis[J]. RSC ADVANCES,2015,5(108):88809-88815.
APA	Li, Yun-Wu.,Ma, Hui-Yan.,Wang, Su-Na.,Xu, Jian.,Li, Da-Cheng.,...&Bu, Xian-He.(2015).Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis.RSC ADVANCES,5(108),88809-88815.
MLA	Li, Yun-Wu,et al."Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis".RSC ADVANCES 5.108(2015):88809-88815.