The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4 | |
Wang, Han1,2; Cao, Hujun1; Wu, Guotao1; He, Teng1; Chen, Ping1 | |
刊名 | energies
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2015-07-01 | |
卷号 | 8期号:7页码:6898-6909 |
关键词 | hydrogen storage amide-hydride system sorption kinetics Li2BNH6 |
英文摘要 | 2mg(nh2)(2)-3lih-libh4 composite exhibits an improved kinetic and thermodynamic properties in hydrogen storage in comparison with 2mg(nh2)(2)-3lih. the peak temperature of hydrogen desorption drops about 10 k and the peak width shrinks about 50 k compared with the neat 2mg(nh2)(2)-3lih. its isothermal dehydrogenation and re-hydrogenation rates are respectively 2 times and 18 times as fast as those of 2mg(nh2)(2)-3lih. a slope desorption region with higher equilibrium pressure is observed. by means of x-ray diffraction (xrd), fourier transform infrared spectroscopy (ftir) and nuclear magnetic resonance (nmr) analyses, the existence of li2bnh6 is identified and its roles in kinetic and thermodynamic enhancement are discussed. |
WOS标题词 | science & technology ; technology |
类目[WOS] | energy & fuels |
研究领域[WOS] | energy & fuels |
关键词[WOS] | mg-n-h ; desorption properties ; hydride system ; libh4 ; complex ; mg(bh4)(2) ; linh2-mgh2 ; kinetics ; imides ; lih |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000359897800034 |
公开日期 | 2016-05-09 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/146478] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Inst Chem Phys, Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Han,Cao, Hujun,Wu, Guotao,et al. The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4[J]. energies,2015,8(7):6898-6909. |
APA | Wang, Han,Cao, Hujun,Wu, Guotao,He, Teng,&Chen, Ping.(2015).The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4.energies,8(7),6898-6909. |
MLA | Wang, Han,et al."The improved Hydrogen Storage Performances of the Multi-Component Composite: 2Mg(NH2)(2)-3LiH-LiBH4".energies 8.7(2015):6898-6909. |
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