Hydrogen peroxide modified Mg-Al-O oxides supported Pt-Sn catalysts for paraffin dehydrogenation
Lai, Yulong1; He, Songbo1,2; Luo, Sha1; Bi, Wenjun1; Li, Xianru1; Sun, Chenglin1; Seshan, K.2
刊名catalysis communications
2015-09-05
卷号69页码:39-42
关键词H2O2 Mg-Al Pt-Sn catalysts Dehydrogenation Paraffin
英文摘要in this work, a new method to prepare mg-al-o oxide by co-precipitation method with addition of h2o2 was developed. the application of mg-al-o as a support of pt-sn catalysts for paraffin dehydrogenation was investigated. characterization results indicated that modification of h2o2 (i) enlarged the pore structure and decreased the density and mechanical strength of the mg-al-o oxide and (ii) increased the platinum dispersion, weakened the acidity of the pt-sn/mg-al-o catalysts. dehydrogenation of n-dodecane results showed that modification of h2o2 (iii) improved the paraffin conversion and olefin selectivity; (iv) inhibited the coke deposition on the catalyst and (v) extended the catalyst life-time. (c) 2015 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]selectivity ; simulation ; olefin ; silica ; size
收录类别SCI
语种英语
WOS记录号WOS:000359885900009
公开日期2016-05-09
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/146472]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Univ Twente, MESA Inst Nanotechnol, Catalyt Proc Mat, NL-7500 AE Enschede, Netherlands
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GB/T 7714
Lai, Yulong,He, Songbo,Luo, Sha,et al. Hydrogen peroxide modified Mg-Al-O oxides supported Pt-Sn catalysts for paraffin dehydrogenation[J]. catalysis communications,2015,69:39-42.
APA Lai, Yulong.,He, Songbo.,Luo, Sha.,Bi, Wenjun.,Li, Xianru.,...&Seshan, K..(2015).Hydrogen peroxide modified Mg-Al-O oxides supported Pt-Sn catalysts for paraffin dehydrogenation.catalysis communications,69,39-42.
MLA Lai, Yulong,et al."Hydrogen peroxide modified Mg-Al-O oxides supported Pt-Sn catalysts for paraffin dehydrogenation".catalysis communications 69(2015):39-42.
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