Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents

	Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents
	Wang, He; Yu, Songjie; Qi, Zisong; Li, Xingwei
刊名	organic letters
	2015-06-05
卷号	17 期号:11 页码:2812-2815
英文摘要	rhodium(iii)-catalyzed direct alkylation of arenes using commercially available alkyltrifluoroborates is disclosed. oximes, heteroarenes, azomethines, n-nitrosoamines, and amides are viable directing groups to entail this transformation. the alkyl group in the boron reagent can be extended to primary alkyls, benzyl, and cycloalkyls, and the reaction proceeded with controllable mono- and dialkylation selectivity when both ortho c-h sites are accessible.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	palladium-catalyzed alkylation ; single-electron transmetalation ; carbon-hydrogen bonds ; aryl boronic acids ; one-pot synthesis ; directing group ; n-phenoxyacetamides ; regioselective synthesis ; arylboron reagents ; organic-synthesis
收录类别	SCI
语种	英语
WOS记录号	WOS:000355962200063
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146322]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, He,Yu, Songjie,Qi, Zisong,et al. Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents[J]. organic letters,2015,17(11):2812-2815.
APA	Wang, He,Yu, Songjie,Qi, Zisong,&Li, Xingwei.(2015).Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents.organic letters,17(11),2812-2815.
MLA	Wang, He,et al."Rh(III)-Catalyzed C-H Alkylation of Arenes Using Alkylboron Reagents".organic letters 17.11(2015):2812-2815.