Total synthesis of (+)-fusarisetin A

	Total synthesis of (+)-fusarisetin A
	Huang, Jun 1; Fang, Lichao 1; Gong, Jianxian 1; Li, Chuangchuang 1; Yang, Zhen 1,2,3
刊名	tetrahedron
	2015-06-03
卷号	71 期号:22 页码:3720-3733
关键词	Stereoselective Fusarisetin A Pauson-Khand reaction trans-Decalin Quaternary stereocenter
英文摘要	herein we report the full details of our efforts toward the application of pauson-khand reaction for the stereoselective construction of the trans-decalin subunit with a c16 quaternary stereocenter of fusarisetin a, which led to the asymmetric total synthesis of (+)-fusarisetin a. the developed chemistry provides an alternative strategy to the intramolecular diels alder reaction that has been employed for the synthesis of trans-decalin based natural products. (c) 2014 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	pauson-khand reaction ; enantioselective total-synthesis ; diels-alder reaction ; fusarium toxin equisetin ; formal total-synthesis ; n-oxide ; carbonyl-compounds ; absolute-configuration ; asymmetric-synthesis ; conjugate reduction
收录类别	SCI
语种	英语
WOS记录号	WOS:000355051000023
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146264]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Peking Univ, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Minist Educ, Beijing 100871, Peoples R China 3.Peking Univ, Peking Tsinghua Ctr Life Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Huang, Jun,Fang, Lichao,Gong, Jianxian,et al. Total synthesis of (+)-fusarisetin A[J]. tetrahedron,2015,71(22):3720-3733.
APA	Huang, Jun,Fang, Lichao,Gong, Jianxian,Li, Chuangchuang,&Yang, Zhen.(2015).Total synthesis of (+)-fusarisetin A.tetrahedron,71(22),3720-3733.
MLA	Huang, Jun,et al."Total synthesis of (+)-fusarisetin A".tetrahedron 71.22(2015):3720-3733.