Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation

	Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation
	Wang, Xu; Lu, Sheng-mei; Li, Jun; Liu, Yan; Li, Can
刊名	catalysis science & technology
	2015
卷号	5 期号:5 页码:2585-2589
英文摘要	a series of chiral conjugated microporous polymers (cmps) based on the chiral (r)-binap ligand (binap-cmps) were synthesized with tunable bet surface areas. these solid catalysts show high activities and enantioselectivities for the asymmetric hydrogenation of beta-keto esters after coordination with ruthenium species. moreover, cmps can realize spatial isolation. through preventing the formation of dimers and trimers, binap-cmps show much higher activity than binap for the ir-catalyzed asymmetric hydrogenation of quinaldine.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	porous organic polymers ; miyaura coupling reaction ; n-heterocyclic carbene ; high-surface-area ; heterogeneous catalyst ; synthetic control ; framework ; networks ; nanoparticles ; epoxidation
收录类别	SCI
语种	英语
WOS记录号	WOS:000353641800006
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146222]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xu,Lu, Sheng-mei,Li, Jun,et al. Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation[J]. catalysis science & technology,2015,5(5):2585-2589.
APA	Wang, Xu,Lu, Sheng-mei,Li, Jun,Liu, Yan,&Li, Can.(2015).Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation.catalysis science & technology,5(5),2585-2589.
MLA	Wang, Xu,et al."Conjugated microporous polymers with chiral BINAP ligand built-in as efficient catalysts for asymmetric hydrogenation".catalysis science & technology 5.5(2015):2585-2589.