Bronsted acid-catalyzed phenylselenenylation of internal olefins

	Bronsted acid-catalyzed phenylselenenylation of internal olefins
	Wu, Ping; Huang, Fei; Lou, Jiang; Wang, Quannan; Liu, Zhuqing; Yu, Zhengkun
刊名	tetrahedron letters
	2015-05-06
卷号	56 期号:19 页码:2488-2491
关键词	Bronsted acid Internal olefins Phenylselenenylation N-phenylselenophthalimide Phenylseleno transfer
英文摘要	bronsted acid p-tsoh center dot h2o-catalyzed phenylselenenylation of alpha-oxo ketene dithioacetals was efficiently achieved, by using n-phenylselenophthalimide (n-psp) as the phenylseleno reagent. the resultant selenated ketene dithioacetals reacted with styrene in the presence of the same acid to undergo phse group transfer, regioselectively affording markovnikov-type phse-alkylated olefins. their further transformation with phenylboronic acid, guanidine, and hydrazine offers a promising route to access s,se-incorporated organic compounds. (c) 2015 elsevier ltd. all rights reserved.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	oxo ketene dithioacetals ; stereoselective-synthesis ; organoselenium chemistry ; efficient synthesis ; bond activation ; alkenes ; carbocyclization ; styrenes ; indoles ; ketones
收录类别	SCI
语种	英语
WOS记录号	WOS:000353751000025
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146212]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Wu, Ping,Huang, Fei,Lou, Jiang,et al. Bronsted acid-catalyzed phenylselenenylation of internal olefins[J]. tetrahedron letters,2015,56(19):2488-2491.
APA	Wu, Ping,Huang, Fei,Lou, Jiang,Wang, Quannan,Liu, Zhuqing,&Yu, Zhengkun.(2015).Bronsted acid-catalyzed phenylselenenylation of internal olefins.tetrahedron letters,56(19),2488-2491.
MLA	Wu, Ping,et al."Bronsted acid-catalyzed phenylselenenylation of internal olefins".tetrahedron letters 56.19(2015):2488-2491.