Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose

	Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose
	Sheng, Xueru 1,2; Li, Ning 1; Li, Guangyi 1; Wang, Wentao 1; Yang, Jinfan 1,2; Cong, Yu 1; Wang, Aiqin 1; Wang, Xiaodong 1; Zhang, Tao 1
刊名	scientific reports
	2015-03-31
卷号	5
英文摘要	for the first time, renewable high density aviation fuels were synthesized at high overall yield (95.6%) by the guerbet reaction of cyclopentanol which can be derived from lignocellulose, followed by the hydrodeoxygenation (hdo). the solvent-free guerbet reaction of cyclopentanol was carried out under the co-catalysis of solid bases and raney metals. among the investigated catalyst systems, the combinations of magnesium-aluminium hydrotalcite (mgal-ht) and raney ni (or raney co) exhibited the best performances. over them, high carbon yield (96.7%) of c-10 and c-15 oxygenates was achieved. the guerbet reaction products were further hydrodeoxygenated to bi(cyclopentane) and tri(cyclopentane) over a series of ni catalysts. these alkanes have high densities (0.86 g ml(-1) and 0.91 g ml(-1)) and can be used as high density aviation fuels or additives to bio-jet fuel. among the investigated hdo catalysts, the 35 wt.% ni-sio2-dp prepared by deposition-precipitation method exhibited the highest activity.
WOS标题词	science & technology
类目[WOS]	multidisciplinary sciences
研究领域[WOS]	science & technology - other topics
关键词[WOS]	high-quality diesel ; pot catalytic conversion ; renewable diesel ; transportation fuels ; liquid alkanes ; range alkanes ; bio-oil ; biomass ; hemicellulose ; hydrodeoxygenation
收录类别	SCI
语种	英语
WOS记录号	WOS:000351947900001
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/146121]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China
推荐引用方式 GB/T 7714	Sheng, Xueru,Li, Ning,Li, Guangyi,et al. Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose[J]. scientific reports,2015,5.
APA	Sheng, Xueru.,Li, Ning.,Li, Guangyi.,Wang, Wentao.,Yang, Jinfan.,...&Zhang, Tao.(2015).Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose.scientific reports,5.
MLA	Sheng, Xueru,et al."Synthesis of high density aviation fuel with cyclopentanol derived from lignocellulose".scientific reports 5(2015).