Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates

	Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates
	Jin, Weiwei 1; Yang, Qin 1; Wu, Ping 1; Chen, Jiping 1; Yu, Zhengkun 1,2
刊名	advanced synthesis & catalysis
	2014-06-16
卷号	356 期号:9 页码:2097-2102
关键词	allyl carbonates allylation C-H activation enones ketene dithioacetals palladium
英文摘要	the palladium-catalyzed oxidative heck-type allylation of beta,beta-disubstitutedenones, i.e., alpha-oxoketene dithioacetals, was efficiently realized with allyl carbonates, providing a concise route to highly functionalized dienes. the present synthetic methodology utilizes the substrate activation strategy to activate the c-h bond of beta,beta-disubstituted enones by introduction of a 1,2-dithiolane functionality to make the enone substrate highly polarized and thus increase its reactivity, demonstrating rare examples for transition metal-catalyzed allylic substitution of beta,beta-disubstituted enones through a heck-type allylation process.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, applied ; chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	oxo ketene dithioacetals ; h bond activation ; efficient synthesis ; simple alkenes ; vinyl ketones ; olefination ; heteroarenes ; derivatives ; zoanthenol ; mechanism
收录类别	SCI ; IC
语种	英语
WOS记录号	WOS:000337609400020
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145763]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Jin, Weiwei,Yang, Qin,Wu, Ping,et al. Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates[J]. advanced synthesis & catalysis,2014,356(9):2097-2102.
APA	Jin, Weiwei,Yang, Qin,Wu, Ping,Chen, Jiping,&Yu, Zhengkun.(2014).Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates.advanced synthesis & catalysis,356(9),2097-2102.
MLA	Jin, Weiwei,et al."Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates".advanced synthesis & catalysis 356.9(2014):2097-2102.