The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions

	The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions
	Shen, Zheng 1,2; Gu, Minyan 1; Zhang, Min 1; Sang, Wenjing 1; Zhou, Xuefei 1; Zhang, Yalei 1; Jin, Fangmin 1
刊名	rsc advances
	2014
卷号	4 期号:29 页码:15256-15263
英文摘要	recently, formate of possible abiogenic origin has been reported from uncatalyzed transfer hydrogenation of co2 with glycerine under alkaline hydrothermal conditions. however, little is known about the mechanism for production of abiogenic formate from co2 and lactate from glycerine during such processes. herein, we investigated the formation of abiogenic formate from co2, d2o solvent effect, reactor materials effect and h2o molecule catalysis for uncatalyzed transfer hydrogenation of co2 with glycerine under alkaline hydrothermal conditions, and then have proposed and proved the potential reaction mechanism. the present work should help facilitate studies on industrial applications of co2 reduction using abundant alcohol compounds as reducing materials rather than hydrogen, and the development of renewable high-valued chemicals from alternative biomass derivatives and the primary greenhouse gas to fossil fuel.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	high-temperature water ; carbon-dioxide ; formic-acid ; lactic-acid ; supercritical water ; transfer reduction ; organic-compounds ; verley reduction ; acrylic-acid ; catalysis
收录类别	SCI
语种	英语
WOS记录号	WOS:000333528900060
公开日期	2016-05-09
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/145718]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Tongji Univ, Natl Engn Res Ctr Facil Agr, State Key Lab Pollut Control & Resources Reuse, Key Lab Yangtze River Water Environm,MOE, Shanghai 200092, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Shen, Zheng,Gu, Minyan,Zhang, Min,et al. The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions[J]. rsc advances,2014,4(29):15256-15263.
APA	Shen, Zheng.,Gu, Minyan.,Zhang, Min.,Sang, Wenjing.,Zhou, Xuefei.,...&Jin, Fangmin.(2014).The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions.rsc advances,4(29),15256-15263.
MLA	Shen, Zheng,et al."The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions".rsc advances 4.29(2014):15256-15263.